工作和學習背景
現在主要從事有機矽、鍺和錫化學,包括官能團化有機矽單體和光學活性聚矽烷合成,穩定的不飽和14-族有機金屬化合物合成及其結構和它們的反應活性的研究。
2005、05-至今 杭州師範大學有機矽化學及材料技術教育部重點實驗室2003/06 – 2005/06 大阪府立大學, 日本學術振興會外國人特別研究員(JSPS),Ogawa 實驗室
1998/09-2003/04 浙江大學有機化學研究所有機化學專業,理學博士學位,
指導老師:張永敏 教授
1994/09-1998/06 河南師範大學化學系化學教育專業,學士學位
論文
2002年以來發表的主要研究論文 1. A New Entry to the Construction of Si-Si Linkage: Sm/SmI2-Induced Efficient Reductive Coupling of Organochlorosilanes
Zhifang Li, Koichiro Iida, Yuri Tomisaka, Aya Yoshimura, Toshikazu Hirao, Akihiro Nomoto, Akiya Ogawa, Organometallics, 2007, 26(5), 1212-1216.
2. FERRIC CHLORIDE-CATALYZED DEOXYGENATIVE CHLORINATION OF CARBONYL COMPOUNDS TO HALIDES,
Zhifang Li, Chunqi Sheng, Huayu Qiu and Yongmin Zhang, Org. Prep. Proc. Int. 2007, 39(4), 429-432.
3. Direct Construction of Silicon-Silicon Bond by Using the Low-Valent Titanium
Guoqiao Lai, Zhifang Li, Jiabang Huang, Jianxiong Jiang, Huayu Qiu, Yongjia Shen, J. Organomet. Chem. 2007, 692, 3559-3562.
4. Controlled Introduction of Allylic Group to Chlorosilanes
Zhifang Li, Xiaojun Cao, Guoqiao Lai, Jinhua Liu, Yong Ni, Jirong Wu, Huayu Qiu, J. Organomet. Chem. 2006, 691, 4740-4746.
5. A Highly Efficient Reduction of Group 14 Heteroatom-Chlorine Single Bonds by Using Samarium Diiodide-Mediated Reaction Systems
Ikuyo Kamiya, Koichiro Iida, Zhifang Li, Yuri Tomisaka, Akiya Ogawa, J. Alloys Comp. 2006, 408-412, 437-440
6. Reductive Dimerization and Polymerization of Organochlorosilanes Mediated by a Sm/SmI2 Mixed System
Zhifang Li, Yuri Tomisaka, Akiya Ogawa, International Symposium Rare Earths’ 04 in Nara, Japan, November 7-12, 2004.
7. Low-Valent Samarium Promoted Reductive Polymerization of Organochlorosilanes
Zhifang Li, Akiya Ogawa, Rare Earths, 2004, 45, 232.
8. Novel Cyclization of Dimeric Dianions of Anils or Aldehydes with Triphosgene: A Safe and Efficient Synthesis of Substituted Imidazolidin –2-ones and 4,5-Diaryl-1,3-dioxolan –2-ones
Zhifang Li and Yongmin Zhang, Heteroatom Chem. 2003, 14 (1) 46-49.
9. Direct construction of quaternary carbon center utilizing an allylsamarium bromide reagent
Zhifang Li and Yongmin Zhang, Tetrahedron 2002, 58 (26), 5301.
10. Direct Construction of Quaternary Carbon Centre Utilizing an Organosamarium Reagent
Zhifang Li and Yognmin Zhang , Tetrahedron Lett. 2002, 42, 8507.
11. Low-Valent Titanium Induced Cyclization of Dimeric Dianions of Anil with Triphosgene: A Safe and Efficient Method for the Synthesis of Substituted Imidazolidine
Zhifang Li and Yongmin Zhang, Synth. Commun. 2002, 32(17), 2613-2618.
國際會議論文
1. International Symposium Rare Earth’ 04 in Nara, Japan,
Reductive Dimerization and Polymerization of Organochlorosilanes Mediated by a Sm/SmI2 Mixed System, Li Zhifang, and Ogawa Akiya
2. China, Korea and Japan Tri-National Symposium on Silicon,2006, 11. 13-15th
Direct Construction of Silicon-Silicon Bond by Using the Low-Valent Titanium, Li Zhifang and Quoqiao Lai
3. 1st Pacific Symposium on Radical Chemistry (PSRC-1), November 15-16, 2004, Kanazawa, Japan
Low-valent Rare Earth Promoted Reaction of Chlorosilanes Li Zhifang, and Ogawa Akiya
主持過的主要科研項目
1. Development of Photo-induced New Catalytic Systems of Rare Earth Complexes (編號P03091, 240萬日元,日本學術振興會,2003年6月 29---2005年6月28)。
2. 稀土金屬催化液晶聚矽烷的合成研究
杭州市留學人員科研活動擇優資助項目 2萬,2006年12月-2007年12月。
3. 有機矽介孔負載催化劑的製備及其對矽氫加成反應的催化性能研究, 4萬,2007,4-2009,3。